For example, austenitic stainless steels such as type 304 or s30400 suffer chronic scc in the presence of hot aqueous solutions containing chloride ions. Mp35n resists corrosion in hydrogen sulphide, salt water and other chloride solutions. An industry value that has been developed is nace mr01. Type 304 stainless steel also known as 188 stainless steel is an austenitic stainless steel.
It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. This is because there remains no direct contact between metal surface and corrosive ions by corrosion products and excess of cations near. Thankyou 304 ss and hydrogen sulfide corrosion engineering engtips. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking.
Sulfide stress cracking an overview sciencedirect topics. If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc the use of cathodic protection for corrosion protection if the process is not properly controlled. Corrosion behavior of austenitic stainless steel in. Stress corrosion cracking behaviour of lean duplex stainless steels in the. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. When they are processed in the refineries, hydrogen sulphide gas h 2 s, which is a toxic gas is produced. The stress corrosion cracking behaviour of uns n08031 in. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media.
Both of type 304 and type 316 stainless steels showed quite similar. Uniform corrosion of the steel in figure 6 above a decrease in corrosion rate as exposure time increases was observed. Hydrogen sulphide cracking is one of the important processes in the oil and gas industry as the hydrocarbons that are produced contain considerable amounts of hydrogen sulphide. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. A comparative h2s corrosion study of 304l and 316l. Corrosionpedia what is sulfide stress cracking ssc. The hydrogen sulphide stress corrosion cracking of tig and laser welded 304 stainless steel in a sulphide containing nace solution was studied with the electrochemical and constant load tests. They may also substitute advantageously carbon steels when maintenance costs are. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Austenitic stainless steels, particularly type 304, are prone to a deposition. Therefore, sulfide precipitates, inclusions and stringers can affect the scc susceptibility in pipeline.
Affect of sulphur containing gas conditionshydrogen and hydrogen sulphide grades such as 1. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Hydrogen sulphide stress corrosion cracking in materials for. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Hydrogenenhanced stress corrosion cracking in stainless steel. Hydrogen sulfide stress corrosion cracking of stainless steels. The generation of corrosion under insulation and stress corrosion. Chloride stress corrosion cracking in austenitic stainless.
The environment causing stresscorrosion cracking scc at the top of a distillation tower in a crude oil refinery was reproduced in the laboratory. The hydrogen sulphide stress corrosion cracking of tig and laser welded 304 stainless steel in a sulphidecontaining nace solution was studied with the electrochemical and constant load tests. Weld metal hydrogen cracking in pipeline girth welds, proc. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Hydrogen sulfide stress corrosion cracking in materials. Sulfide stress cracning ssc is a form of hydrogen embrittlement which is.
Hydrogen sulfide is a chemical compound with the formula h 2 s, and is often a colorless gas with a rotten egg odor, commonly referred to as sewer gas. This paper reports a study of the effects of sulfur and phosphorus on the sensitization and intergranular corrosion of 304 stainless steel. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Ais1 and aci standard composition ranges for wrought and cast chromiumnickel stainless steels r american iron and steel institute classification of chromiumnickel stainless steels composition, y0 aisi type 201 202 301 302 302b 303 303se 304 304l 305 308 309 309s 310 310s 314 316 316l 317 d319 321 347 348 384. It was an acidified hydrogen sulfide solution with a.
Stress corrosion cracking scc results from the combined action of three factors. Stress corrosion cracking behaviour of lean duplex. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Stress corrosion cracking facts and how to reduce the. Stress corrosion cracking applies only to austenitic stainless steels and depends on the nickel content. Corrosion of steels in sour gas environments international nuclear. Factors in sulfide corrosion cracking of high strength. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Processes or conditions involving wet hydrogen sulfide, i. Corrosion testing lab,stress corrosion,materials,hydrogen.
Wet hydrogen sulfide h2s cracking inspectioneering. The effects of sulfide stress cracking on the mechanical properties. The susceptibility to stress corrosion cracking scc of the austenitic stainless steels 304l. Stress corrosion cracking scc is characterized by cracks propagating either. Mp35n is an age hardenable nickelcobalt base alloy that has a unique combination of properties ultra high strength, toughness, ductility and outstanding corrosion resistance. Stress corrosion cracking facts and how to reduce the risk. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of.
As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. Hydrogen cracking its causes, costs and future occurrence. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking of stainless steels in hydrogen. Tests include stress corrosion cracking scc,hydrogen induced cracking test hic, sulfide stress corrosion cracking sscc, intergranular corrosion igc and sulfide stress corrosion cracking sscc at elevated temperature,india,maharashtra,mumbai,bombay,asia. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. However, only scc tests were performed here because industrial experience and an earlier ballot had been successful in demonstrating that ssc and ghsc were not.
It should not be confused with the term stress corrosion cracking which is. Sulphide stress corrosion cracking sscc laboratory. Is type 304 stainless steel a suitable material for a sludge storage tank where the sludge will have a hydrogen sulfide concentration of 5,600 ppm v. Pdf sulfide stress corrosion cracking and hydrogen.
It is shown that sulfur has little effect on the intergranular corrosion of the material, except at the high electrochemical potentials of. The cracking is affected by environmental conditions such as hydrogen sulfide partial pressure and temperature. This alloy was first developed by firth brown steels nearly a century ago. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Environmental cracking of stainless and nibase alloys hydrogen sulfide corrosion acidic environments. The effects of rolling temperature and sensitization. Hydrogen sulphide stress corrosion cracking of weld. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Stress corrosion cracking of a 304 stainless steel elbow.
Clinton offers sae 304 stainless steel, which can also be found under the name a2 stainless steel or 188 stainless steel. It is an austenite steel, meaning that it is nonmagnetic in nature. Sulphide stress cracking ssc is the biggest concern 9. Also, nickel can consume 15% percent its own volume in hydrogen as it approaches high temperatures. Stress corrosion cracking behavior of nickel base alloys. Corrosion of metal and concrete is a major issue associated with the generation and oxidation of hydrogen sulfide. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Mild steel is a popular structural steel in this industry but is susceptible to surface scale formation and associated corrosive action, the prevention of which requires some.
The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. The effects of sulfur and phosphorus on the intergranular. It also has excellent resistance to crevice and stress corrosion cracking in sea water and other hostile environments. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by.
The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Cracking threshold stress is very high, and is assumed to be about 100kgmm 2. To check its resistance to scc and ssc, several tests were performed. Ebrahimia a department of materials science and engineering, faculty of engineering, sabzevar tarbiat moallem university, iran bdepartment of materials science and engineering, school of engineering, shiraz university, iran. The cracking was found when rust stainingleaks were observed. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Hydrogen sulphide stress corrosion cracking of tig and. Wet h2s cracking occurs due to the effects of aqueous hydrogen charging of. Protection of metal from the hydrogen sulfide corrosion. Sulfide stress cracking ssc vs hydrogen induced cracking. A comparative h 2s corrosion study of 304l and 316l stainless steels in acidic media a.
A surface crack in the steel for the corrosive agent to enter select one. Sulphide stress cracking sulphide stress cracking is an important failure mode in the oil industry, where the steel comes into contact with. Cracking and stress corrosion cracking resistance in sour oilfield environments and is clearly focused on oilfield production. Sour service limits of dualcertified 316316l steel twi. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Corrosion testing lab services,hydrogen induced disbonding laboratory,stress corrosion testing lab as per astm,nace standards. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Alloys which are commercially available and those which have modified metallurgical structures and. A corrosive medium especially chloridebearing or hydrogensulphide h2s media. Stress corrosion cracking issues in syngas plants that may. Corrosion science volume 40, issues 45, aprilmay 1998, pages 577591 hydrogen sulphide stress corrosion cracking of weld overlays for desulfurization reactors. In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of brine or salt water introduces the additional issue of. Corrosion inhibitors for systems with a high content of hydrogen sulphide h2s in the produced fluids since the discovery and development of oil and gas fields containing hydrogen sulfide in the production wells, the problem of protection of metal from the hydrogen sulfide corrosion arose acutely. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking.